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What are the common methods for removing moisture, carbon dioxide, and acetylene from the air when air enters the air separation equipment?

What are the common methods for removing moisture, carbon dioxide, and acetylene from the air when air enters the air separation equipment?
Mar 07, 2024
Author: DEAR AST

The most commonly used methods for removing moisture, carbon dioxide, and acetylene from the air are adsorption and freezing.

The adsorption method uses silica gel or molecular sieves as adsorbents to separate impurities such as water, carbon dioxide, and acetylene from the air, as well as acetylene from liquid air and liquid oxygen, and concentrate them on the surface of the adsorbent (without chemical reaction). When heated and regenerated, they are then removed to achieve the purpose of purification. For example, setting up dryers, carbon dioxide adsorbers, liquid air adsorbers, and liquid oxygen adsorbers.

The freezing method is to freeze the moisture and carbon dioxide contained in the air when it passes through a cold storage or switching heat exchanger (acetylene cannot freeze), and then be carried out of the device by dry backflow gas, which is self clearing.

In high-pressure, medium pressure, high and low-pressure oxygen production systems, the alkaline washing method was used to remove carbon dioxide, that is, using an aqueous solution of sodium hydroxide (Na0H) to absorb carbon dioxide from the air. Due to inconvenience in operation, it has been phased out.

The use of molecular sieve purification process can simultaneously adsorb and remove moisture, carbon dioxide, and acetylene from the air, simplifying the process. It has been widely used in oxygen concentrators.

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When the amount of processing air is reduced, the rising steam and reflux liquid in the upper column will be reduced, but the reflux ratio will not change. Therefore, the reduction of processing air in a small range will not affect the purity of oxygen and nitrogen, and the reduction of processing air volume will help to reduce the pressure of the upper and lower columns. However, according to the material balance, the production of oxygen and nitrogen will naturally decrease when the amount of processing air is reduced. If the amount of processing air is too small, there will be leakage on the tray. If the heat and mass exchange of the leaked liquid is not sufficient, the purity of oxygen and nitrogen will be greatly affected, and even the normal production can not be realized. Therefore, the minimum allowable load of distillation column is generally specified.
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