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What is the effect of insufficient processing air on distillation conditions

What is the effect of insufficient processing air on distillation conditions
Feb 13, 2023
Author: DEAR AST

When the air volume decreases, the rising steam volume and reflux liquid volume in the tower decrease, but the reflux ratio remains unchanged. Under normal conditions, it has little effect on the purity of oxygen and nitrogen products. According to the material balance, when the amount of processing air decreases, the output of oxygen and nitrogen will decrease accordingly.

When the gas volume decreases, the steam flow rate decreases, the liquid volume on the tray also decreases, and the liquid layer thins, so the tray resistance decreases. At the same time, as the main cooling and heating load is reduced, the heat transfer area is rich, and the heat transfer temperature difference can also be reduced. These effects will help to reduce the pressure of the upper and lower towers.

When the gas volume is reduced too much, the liquid on the sieve hole may not be held due to the low gas velocity, and the liquid will leak directly from the sieve hole, resulting in liquid leakage. The leaked liquid does not fully contact with the steam, part of the evaporation is not sufficient, and the nitrogen concentration is high. This will greatly reduce the distillation effect, affect the purity of product oxygen and nitrogen, and even fail to maintain normal production in serious cases. Therefore, the minimum allowable load value is specified for the distillation column, which is related to the structural type of the tray and the selection of parameters during design.

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The amount of liquid nitrogen removed from the lower column of the air separation unit will affect the purity of the liquid nitrogen in the lower column and the oxygen enriched liquid air at the bottom of the column. When the liquid nitrogen removal amount of the lower column increases, the reflux liquid participating in the heat and mass exchange of the lower column will be reduced, the temperature rise of the rising steam on the column plate will be correspondingly reduced, the condensation of the rising steam will not be sufficient, the oxygen component will be condensed less, the purity of nitrogen at the column top will be reduced, and the purity of liquid nitrogen will be naturally reduced. At the same time, the temperature rise of the downflow liquid will increase, the liquid evaporation will be more sufficient, more nitrogen components will be evaporated to the top of the column, and the purity of the liquid air at the bottom of the column will be improved accordingly.
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