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Why must molecular sieves be used for cryogenic air separation equipment?

Why must molecular sieves be used for cryogenic air separation equipment?
May 07, 2026
Author: DEAR AST

Modern cryogenic air separation equipment must be equipped with molecular sieve purification system, which is the core premise to ensure long-term safe and stable operation of equipment. The combination of alkali washing and drying tower was used for the old plant in the early stage, but the purification accuracy was low and the energy consumption was high, which had been replaced by molecular sieve. The cryogenic air separation without molecular sieve was only applicable to very small test units or temporary working conditions, and long-term production could not be realized.
The core function of molecular sieve is to deeply remove water, carbon dioxide and hydrocarbon impurities in the air under normal temperature. The residual water after precooling will freeze when entering the - 170 ℃ - - 190 ℃ cold box, and the carbon dioxide will solidify into dry ice, which will block the heat exchanger and rectification tower, resulting in equipment shutdown; Molecular sieve can remove water to dew point ≤ - 70 ℃ and carbon dioxide to ≤ 1ppm to completely avoid blocking.
More importantly, molecular sieve can eliminate the explosion risk. Trace amount of acetylene and other hydrocarbons in the air are easy to be concentrated in liquid oxygen, which is very easy to cause accidents after reaching the explosion limit. The molecular sieve can remove acetylene to ≤ 0.01ppm, and build a solid security line.
In addition, the molecular sieve has high adsorption efficiency and strong selectivity. With the double-column alternate working mode, it can realize uninterrupted gas supply. In addition, the energy consumption is far lower than the traditional method by using the polluted nitrogen for regeneration, and its function cannot be replaced by silica gel, activated alumina and other materials. It is an indispensable key component of the cryogenic air separation equipment.

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1. Before filling with pearlite, the water accumulated on the foundation surface of air separation unit must be removed, dried with hot air, and all manholes shall be closed. 2. When filling pearlite, all containers and pipes in the cold box should be inflated and kept at 50kPa pressure, then slightly open the valve of each meter pipeline, and all thermometers should be electrified to check whether the thermometer cable is damaged during the filling process. 3. The filled pearlite shall not be mixed with combustibles. 4. When filling with pearlite, coarse mesh or pearlite pouring device should be set at the manhole on the top of the cold box to prevent whole bag pearlite from entering the cold box. 5. After the pearlite is filled, the manhole shall be sealed.
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