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How does the energy of air in air separation equipment change after isothermal compression?

How does the energy of air in air separation equipment change after isothermal compression?
Nov 18, 2024
Author: DEAR AST

After isothermal compression, the energy of air will change, resulting in a decrease in internal energy.
During isothermal compression, the temperature of the air remains constant. Since temperature is a marker of the average kinetic energy of molecules, a constant temperature means that the average kinetic energy of gas molecules in motion remains unchanged. During isothermal compression, as the gas is compressed, the distance between molecules decreases. This leads to a decrease in the potential energy of intermolecular interactions, as the attractive and repulsive forces between molecules decrease with decreasing distance, but in this case, the main manifestation is a decrease in repulsive force, resulting in a decrease in potential energy. Due to the constant temperature, the average kinetic energy of gas molecules remains unchanged, so the kinetic energy portion has not changed. The reduction of molecular spacing leads to a decrease in the potential energy of intermolecular interactions, which is the main reason for the energy reduction during isothermal compression.
In the process of air compression, electricity is usually consumed to increase the air pressure. At the same time, the temperature of the gas will also increase. But in order to achieve isothermal compression, measures need to be taken to reduce the heat generated during the compression process and maintain the temperature constant. These cooling measures actually take away some energy, further reducing the internal energy of the compressed air.

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When the amount of processing air is reduced, the rising steam and reflux liquid in the upper column will be reduced, but the reflux ratio will not change. Therefore, the reduction of processing air in a small range will not affect the purity of oxygen and nitrogen, and the reduction of processing air volume will help to reduce the pressure of the upper and lower columns. However, according to the material balance, the production of oxygen and nitrogen will naturally decrease when the amount of processing air is reduced. If the amount of processing air is too small, there will be leakage on the tray. If the heat and mass exchange of the leaked liquid is not sufficient, the purity of oxygen and nitrogen will be greatly affected, and even the normal production can not be realized. Therefore, the minimum allowable load of distillation column is generally specified.
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