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What are the functions and classification of the rectifying column of air separation equipment?

What are the functions and classification of the rectifying column of air separation equipment?
Apr 20, 2026
Author: DEAR AST

The rectifying column of air separation equipment is the core device of cryogenic air separation. Its core function is to realize the efficient separation and purification of air components through multi-stage gas-liquid contact by utilizing the boiling point difference of oxygen, nitrogen, argon and other components, so as to provide high-purity gas products for industrial production.
Its core functions mainly include three aspects: first, separation and purification, by virtue of boiling point difference of components, through countercurrent contact of gas and liquid, mass transfer and heat transfer, high purity nitrogen is obtained at the top of the column, high purity oxygen is obtained at the bottom of the column, and argon fraction can be extracted from the side line; The second is efficient gas-liquid contact, which provides phase interface through tray or packing to ensure full gas-liquid contact without entrainment and improve separation efficiency; The third is cooling capacity circulation and impurities removal. The cooling capacity circulation is realized by cooperating with the condensing evaporator. Meanwhile, impurities such as carbon dioxide and water are removed to ensure product purity.
The rectifying column can be divided into plate column and packed column according to the gas-liquid contact mode. The plate column has large operation flexibility and is applicable to large high-pressure air separation; The packed column pressure is reduced, suitable for low-pressure high-purity separation. It can be divided into single stage and double stages according to the rectification stage. The double stage (double column) consists of high pressure lower column and low pressure upper column. It is a standard configuration for modern air separation, and can obtain high purity oxygen and nitrogen efficiently. In addition, it can be divided into main rectification column, argon column system and rare gas column according to functions, corresponding to main separation, argon purification and rare gas extraction respectively.

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When the amount of processing air is reduced, the rising steam and reflux liquid in the upper column will be reduced, but the reflux ratio will not change. Therefore, the reduction of processing air in a small range will not affect the purity of oxygen and nitrogen, and the reduction of processing air volume will help to reduce the pressure of the upper and lower columns. However, according to the material balance, the production of oxygen and nitrogen will naturally decrease when the amount of processing air is reduced. If the amount of processing air is too small, there will be leakage on the tray. If the heat and mass exchange of the leaked liquid is not sufficient, the purity of oxygen and nitrogen will be greatly affected, and even the normal production can not be realized. Therefore, the minimum allowable load of distillation column is generally specified.
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